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dc.contributor.authorAcar, Yasemin
dc.contributor.authorKara, Hülya
dc.contributor.authorGüngör, Elif
dc.contributor.authorÇoban, Mustafa Burak
dc.date.accessioned2019-08-06T12:16:39Z
dc.date.available2019-08-06T12:16:39Z
dc.date.issued2018en_US
dc.identifier.issn1542-1406
dc.identifier.issn1563-5287
dc.identifier.urihttps://doi.org/10.1080/15421406.2018.1467092
dc.identifier.urihttps://hdl.handle.net/20.500.12462/5893
dc.description.abstractA new chloride bridged polymeric Cu(II) complex, [Cu(HL)(-Cl).H2O](n), 1, (H2L = 2,4-dichloro-6-{[(2-hydroxyethyl)imino]methyl}phenol) has been synthesized and characterized by elemental-spectral analysis, crystal structure analysis and photoluminescence measurements. The Copper(II) atom is five-coordinate in a slightly distorted square-pyramidal geometry ( = 0.085), with one N and two O atoms of the Schiff base ligand and one Cl atom defining the basal plane and a symmetry-related Cl atom occupying the apical position. The bridging Cl atom lies in apical position for one Cu(II) ion and basal for the other, and it makes this structural arrangement unusual. The linked moieties form polymeric zigzag chains running along the c axis. This zigzag chains connect each other with intramolecular and intermolecular O-HO hydrogen bonds, which form 3D structure through - interactions. Furthermore, the photoluminescence properties of H2L and 1 were investigated, they exhibit unique bright green visible emissions in the solid state, under the excitation of 349nm UV light. The strong luminescence emission of them makes 1 a potentially useful photoactive material in photo-physical chemistry.en_US
dc.description.sponsorshipBalikesir University - BAP-2017 / 161en_US
dc.language.isoengen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.isversionof10.1080/15421406.2018.1467092en_US
dc.rightsinfo:eu-repo/semantics/embargoedAccessen_US
dc.subjectCrystal Structure Analysisen_US
dc.subjectPolymeric Cu(II) Complexen_US
dc.subjectPhotoluminescenceen_US
dc.titleCatena-poly[[[2,4-dichloro-6-{[(2-hydroxyethyl)imino]methyl}phenolato-n-3,o,o']-copper(ıı)]--chlorido]monohydrate]: synthesis, structural, spectroscopic and luminescent propertiesen_US
dc.typearticleen_US
dc.relation.journalMolecular Crystals and Liquid Crystalsen_US
dc.contributor.departmentFen Edebiyat Fakültesien_US
dc.contributor.authorID0000-0003-3488-5284en_US
dc.identifier.volume664en_US
dc.identifier.issue1en_US
dc.identifier.startpage165en_US
dc.identifier.endpage174en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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