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dc.contributor.authorAzizoğlu, Akın
dc.contributor.authorYıldız, Cem Burak
dc.date.accessioned2019-10-16T10:53:50Z
dc.date.available2019-10-16T10:53:50Z
dc.date.issued2010en_US
dc.identifier.issn0276-7333
dc.identifier.urihttps://doi.org/10.1021/om100868b
dc.identifier.urihttps://hdl.handle.net/20.500.12462/6921
dc.descriptionAzizoğlu, Akın (Balikesir Author)en_US
dc.description.abstractDensity functional theory and ab initio quantum mechanical calculations elucidated the ring opening reactions of 1 bromo 1 lithiosilirane (3) and 2 bromo 2 lithiosilirane (4) to 2 silallene (6) and 1 silaallene (7) respectively The ring opening of 3 to 6 can proceed in a stepwise fashion with the intermediacy of a free silacyclopropylidene (9) Here a high energy barrier needs to be overcome in order to open the silacyclopropylidene ring and to generate 6 On the contrary the ring opening of 4 to 7 can occur in a concerted fashionen_US
dc.description.sponsorshipScientific and Technical Research Council of Turkey (TUBITAK)en_US
dc.language.isoengen_US
dc.publisherAmer Chemıcal Socen_US
dc.relation.isversionof10.1021/om100868ben_US
dc.rightsinfo:eu-repo/semantics/embargoedAccessen_US
dc.titleRing-opening mechanism of lithium bromosilacyclopropylidenoids to silaallenesen_US
dc.typearticleen_US
dc.relation.journalOrganometallıcsen_US
dc.contributor.departmentFen Edebiyat Fakültesien_US
dc.contributor.authorID0000-0002-0424-4673en_US
dc.contributor.authorID0000-0002-5098-1842en_US
dc.identifier.volume29en_US
dc.identifier.issue24en_US
dc.identifier.startpage6739en_US
dc.identifier.endpage6743en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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