Spectrometric determination of iron and copper in vegetable oils after separation with schiff base impregnated silica gel column: a simple approach for eliminating the high organic matrix

Abstract

A simple solid-phase extraction method has been described for the separation of Fe(III) and Cu(II) from liquid vegetable oils using N,N'-bis(4-methoxy salicylidene) ethylenediamine impregnated silica gel and the determination of these ions. The experimental parameters that affect the separation/preconcentration of ions were investigated by batch and column methods prior to the determination by flame atomic absorption spectrometry. Fe(III) and Cu(II) ions in 20.0 g portion of oil samples can be quantitatively sorbed and then eluted completely with 5.0 mL of 2.0 mol L-1 HNO3. Limits of detection were calculated as 22.8 and 13.9 lg kg(-1) for Fe(III) and Cu(II), respectively. The repetition of the suggested method was checked by finding relative standard deviation for five repeated analyses, which was 1.5% for Fe(III) and 0.1% for Cu(II). Applicability of the method was controlled with spiked and unspiked sunflower, corn, canola, olive, soya and hazelnut oils