dc.contributor.author | Başaran, İsmet | |
dc.contributor.author | Çakır, Ümit | |
dc.date.accessioned | 2019-10-17T10:51:25Z | |
dc.date.available | 2019-10-17T10:51:25Z | |
dc.date.issued | 2014 | en_US |
dc.identifier.issn | 1388-3127 | |
dc.identifier.issn | 1573-1111 | |
dc.identifier.uri | https://doi.org/10.1007/s10847-013-0286-1 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12462/8282 | |
dc.description | Çakır, Ümit (Balıkesir Author) | en_US |
dc.description.abstract | o-Dihydroxy-3-(methylphenyl)-chromenones (coumarins; 3a-3c) were synthesized from trimethoxy-benzaldehydes through a reaction with the corresponding methylphenyl-acrylonitrile in pyridine center dot HCl and then H3O+. Dihydroxycoumarins reacted with the ditosylate or dichloride derivatives of tri-or tetraethyleneglycols in the presence of CH3CN/Na2CO3 and macrocyclic ethers with a coumarin moiety were obtained. The chromatographically purified new coumarin-crown ethers (5a-5f) were identified by IR, H-1 NMR, and Mass spectrometry. The binding constants of Na+ with the coumarin-crown ethers were determined in an 80 % dioxane/water binary solvent system at 25 degrees C from conductance measurements. | en_US |
dc.description.sponsorship | yok | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Springer | en_US |
dc.relation.isversionof | 10.1007/s10847-013-0286-1 | en_US |
dc.rights | info:eu-repo/semantics/embargoedAccess | en_US |
dc.subject | Coumarin-Crown Ethers | en_US |
dc.subject | Synthesis | en_US |
dc.subject | Complexation | en_US |
dc.subject | Conductometry | en_US |
dc.title | The synthesis, Na+ binding properties of new coumarin-crown ethers | en_US |
dc.type | article | en_US |
dc.relation.journal | Journal of Inclusion Phenomena and Macrocyclic Chemistry | en_US |
dc.contributor.department | Fen Edebiyat Fakültesi | en_US |
dc.contributor.authorID | 0000-0001-7641-8938 | en_US |
dc.identifier.volume | 78 | en_US |
dc.identifier.issue | 1-4 | en_US |
dc.identifier.startpage | 179 | en_US |
dc.identifier.endpage | 184 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |